Titanium

TRANSITION METAL · GROUP 4 · PERIOD 4
22
Ti
Titanium
47.867

Atomic Data

Atomic Number22
SymbolTi
Atomic Weight47.867 u
Density (STP)4.506 g/cm³
Melting Point1667.85 °C (1941 K)
Boiling Point3286.85 °C (3560 K)
Electronegativity1.54 (Pauling)
Electron Config.1s2 2s2 2p6 3s2 3p6 3d2 4s2
Oxidation States+2, +3, +4
Phase at STPSolid
CategoryTransition metal
Period / Group4 / 4
CAS Number7440-32-6

Electron Configuration

Ti K L M 10 electrons N

[Ar] 3d2 4s2

Shell n Subshell Electrons Cumulative
K11s22
L22s24
L22p610
M33s212
M33p618
M33d220
N44s222
Total 22 22

Isotopes of Titanium

Titanium has five stable naturally occurring isotopes. ⁴⁸Ti dominates at 73.72% abundance; the remaining four isotopes each account for less than 9% of natural titanium.

Isotope Symbol Protons Neutrons Abundance Stability
Titanium-46 ⁴⁶Ti 22 24 8.25% Stable
Titanium-47 ⁴⁷Ti 22 25 7.44% Stable
Titanium-48 ⁴⁸Ti 22 26 73.72% Stable
Titanium-49 ⁴⁹Ti 22 27 5.41% Stable
Titanium-50 ⁵₀Ti 22 28 5.18% Stable

Abundance & Occurrence

Titanium is the ninth most abundant element in Earth’s crust, found primarily in the minerals ilmenite (FeTiO₃) and rutile (TiO₂). Major deposits occur in Australia, South Africa, Canada, and India; ilmenite is by far the dominant ore mined globally for titanium production.

Earth's Crust (ppm by mass)

Titanium
5,650 ppm
Silicon (ref.)
277,000 ppm
Oxygen (ref.)
461,000 ppm

Universe (ppm by mass)

Titanium
3 ppm
Helium (ref.)
230,000 ppm
Hydrogen (ref.)
739,000 ppm

Discovery & History

1791
William Gregor — A Cornish clergyman and amateur mineralogist discovered an unusual black sand (ilmenite) in the Manaccan valley, Cornwall. He isolated an impure oxide of a new element and called it manaccanite, publishing his findings that year.
1795
Martin Heinrich Klaproth — The German chemist independently identified the same element in rutile ore and named it titanium after the Titans of Greek mythology — beings of great strength — anticipating the metal’s mechanical properties. He later acknowledged Gregor’s prior discovery.
1910
Matthew Hunter — First produced commercially pure titanium metal by reducing titanium tetrachloride (TiCl₄) with sodium in a sealed steel container. This “Hunter process” yielded titanium of about 99.9% purity for the first time.
1940
Wilhelm Kroll — Developed the Kroll process, reducing TiCl₄ with magnesium in an inert atmosphere. More efficient and scalable than the Hunter process, it became the global standard for commercial titanium production and remains so today.

Safety & Handling

  • Dust and powder fire hazard: Titanium metal in bulk is not reactive under normal conditions, but fine titanium powder and swarf are flammable and can ignite spontaneously. Machining or grinding produces fine particles that require dry-sand or Class D fire extinguishers — never water or CO₂, which can intensify a titanium fire.
  • Biocompatibility: Solid titanium is non-toxic and one of the most biocompatible structural metals known. It is not absorbed by the body, does not corrode in physiological fluids, and provokes minimal immune response, making it safe for permanent implants.
  • Titanium tetrachloride (TiCl₄) hazard: The main precursor chemical used in refining reacts violently with moisture, releasing corrosive hydrogen chloride (HCl) fumes. Handling requires full protective equipment and dry, inert-atmosphere conditions.
  • Titanium dioxide (TiO₂): Classified as a possible human carcinogen (IARC Group 2B) when inhaled as fine dust or nanoparticles over prolonged periods; standard dust-control measures and respiratory protection apply in industrial settings.
  • General handling: Bulk titanium components and alloys present minimal health risk. Good ventilation and standard metalworking practices are sufficient; keep powders away from ignition sources and oxidising agents.

Real-World Uses

  • Aerospace structural components — Titanium alloys are used extensively in airframe structures, jet engine fan blades, compressor discs, and spacecraft because they combine near-steel strength with roughly half the weight, and resist the corrosion and fatigue that occur at altitude.
  • Biomedical implants — Hip and knee joint replacements, dental implants, bone screws, and spinal rods are routinely made from titanium alloys (especially Ti-6Al-4V) because the metal integrates directly with bone tissue and remains inert for decades in the body.
  • White pigment (TiO₂) — Titanium dioxide is the world’s most widely used white pigment, providing brightness and opacity in paints, coatings, plastics, paper, inks, and cosmetics; it also serves as the UV-blocking agent in physical sunscreens.
  • Desalination plants — Titanium heat exchangers and pipe systems resist the highly corrosive saltwater environment inside desalination facilities, lasting far longer than stainless steel alternatives at a competitive lifecycle cost.
  • Sporting goods — High-performance bicycle frames, golf club heads, tennis racket frames, and climbing gear use titanium alloys to achieve the stiffness and strength of steel at a fraction of the weight.

Downloadable Resources

Free periodic table reference sheets for classrooms, study sessions, and laboratory use.

Frequently Asked Questions

Why is titanium used in aerospace?

Titanium has one of the highest strength-to-weight ratios of any metal, roughly equivalent in strength to steel at about 45% of the weight. It also withstands the temperature extremes and corrosive environments encountered in jet engines and airframes, making it indispensable for aircraft structures, turbine blades, and spacecraft components.

Is titanium safe in the human body?

Titanium is highly biocompatible — it is non-toxic, non-allergenic, and integrates with living bone tissue through a process called osseointegration. These properties make it the material of choice for dental implants, joint replacements, bone screws, and surgical instruments.

What is titanium dioxide used for?

Titanium dioxide (TiO₂) is the world’s most widely used white pigment, giving brightness and opacity to paints, coatings, plastics, paper, and cosmetics. It is also used in sunscreens as a UV-blocking agent, and in food products as a whitening additive (E171).

Who discovered titanium?

William Gregor, a Cornish clergyman and amateur mineralogist, first identified titanium in 1791 from an iron-bearing black sand (ilmenite) found in Manaccan, Cornwall. He called the new oxide ‘manaccanite’. The element was independently rediscovered in 1795 by Martin Heinrich Klaproth, who named it titanium after the Titans of Greek mythology.