Promethium

LANTHANOID · GROUP None · PERIOD 6
61
Pm
Promethium
145

Atomic Data

Atomic Number61
SymbolPm
Atomic Weight145 u
Density (STP)7.26 g/cm³
Melting Point1041.85 °C (1315 K)
Boiling Point2999.85 °C (3273 K)
Electronegativity1.13 (Pauling)
Electron Config.1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f5 5s2 5p6 6s2
Oxidation States+3
Phase at STPSolid
CategoryLanthanoid
Period / Group6 / None
CAS Number7440-12-2

Electron Configuration

[Xe] 4f5 6s2

Shell n Subshell Electrons Cumulative
K11s22
L22s24
L22p610
M33s212
M33p618
M33d1028
N44s230
N44p636
N44d1046
N44f551
O55s253
O55p659
P66s261
Total 61 61

Isotopes of Promethium

Promethium has two naturally occurring stable isotopes. The most abundant is ¹⁴⁵Pm, comprising None% of all naturally occurring Promethium.

Isotope Symbol Protons Neutrons Abundance Stability
Promethium-145¹⁴⁵Pm6184traceStable
Promethium-147¹⁴⁷Pm6186traceStable

Abundance & Occurrence

Promethium is present in Earth's crust at approximately trace amounts by mass and at approximately trace amounts by mass throughout the universe.

Earth's Crust (ppm by mass)

Promethium
None ppm
Silicon (ref.)
277,000 ppm
Oxygen (ref.)
461,000 ppm

Universe (ppm by mass)

Promethium
None ppm
Helium (ref.)
230,000 ppm
Hydrogen (ref.)
739,000 ppm

Discovery & History

1902
Bohuslav Brauner: Czech chemist Brauner predicted a missing element between neodymium and samarium in the periodic table, though no one could isolate it from natural sources: it would later be explained by its extreme instability.
1945
Jacob A. Marinsky, Lawrence E. Glendenin & Charles D. Coryell: Marinsky, Glendenin, and Coryell identified promethium among the fission products of uranium-235 in the Oak Ridge reactor, using ion-exchange chromatography: naming it after the Titan Prometheus to reflect its fiery nuclear origin.
1963
Oak Ridge National Laboratory: Promethium-147 was produced in gram quantities for the first time, enabling its use as a beta source in luminous paint and nuclear batteries for spacecraft and pacemakers.

Safety & Handling

  • Radioactivity: all isotopes: Promethium has no stable isotopes; all are radioactive. Pm-147 (t½ = 2.6 years, beta emitter) is the principal commercial isotope and requires handling as a radioactive material under licence.
  • Beta radiation: Pm-147 is a moderate-energy beta emitter; external skin dose is of moderate concern, but ingestion or inhalation of promethium presents the greater internal dose hazard: airborne particulate must be contained.
  • Controlled area working: All promethium work must take place in a radiologically controlled area with appropriate contamination monitoring, personal dosimetry, and waste management.
  • Natural absence: Promethium does not occur in nature in macroscopic quantities; it is always a produced material, and quantities in use are tightly regulated and inventoried under national radiation protection regulations.

Real-World Uses

  • Radioisotope power sources: Promethium-147 (t½ = 2.6 yr) beta particles are used in thin-film betavoltaic nuclear batteries that powered early cardiac pacemakers and guided missile systems; compact long-life power sources for remote sensors remain a research interest.
  • Thickness gauging: Pm-147 beta sources are used in precision industrial thickness gauges for measuring sheet metal, paper, plastic film, and textile thickness during continuous manufacturing, exploiting beta-particle attenuation through the material.
  • Scientific research: As the only naturally absent element between bismuth and plutonium, promethium is studied to understand lanthanide chemistry, nuclear structure, and the s-process of nucleosynthesis in stars.

Downloadable Resources

Free periodic table reference sheets for classrooms, study sessions, and laboratory use.

Frequently Asked Questions

Has promethium ever been used for anything?

Promethium-147 has been used in promethium-powered atomic batteries (betavoltaic devices) for pacemakers and guided missile guidance systems during the Cold War era, before lithium batteries became standard. It has also been used in luminescent paint for instrument dials (as a replacement for radium) and in some thickness-measuring gauges. Its radioactivity limits practical applications.

Why is promethium radioactive?

All isotopes of promethium are radioactive because, like technetium (element 43), promethium's position in the periodic table at atomic number 61 means no stable nucleus exists: the nuclear binding energy for any combination of 61 protons and neutrons does not produce stability. The most stable isotope, Pm-145, has a half-life of only 17.7 years, so any primordial promethium has long since decayed.

How was promethium discovered?

Promethium was definitively identified in 1945 by Jacob Marinsky, Lawrence Glendenin, and Charles Coryell at Oak Ridge National Laboratory while analysing uranium fission products from a nuclear reactor. They isolated it by ion exchange chromatography. The element was named after Prometheus, the Titan of Greek mythology who stole fire from the gods, symbolising the nuclear fire used in its discovery.

Does promethium occur naturally on Earth?

Traces of promethium-147 and promethium-145 have been detected in uranium ores, produced by spontaneous fission of uranium and neutron capture processes. However, the amounts are extraordinarily small: estimated at about 572 grams of Pm-147 in Earth's entire crust at any given moment. Effectively, all useful quantities of promethium are produced artificially in nuclear reactors.