Mendelevium

ACTINOID · GROUP None · PERIOD 7
101
Md
Mendelevium
258

Atomic Data

Atomic Number101
SymbolMd
Atomic Weight258 u
Density (STP)N/A
Melting Point826.85 °C (1100 K)
Boiling PointN/A °C (None K)
Electronegativity1.3 (Pauling)
Electron Config.1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 5f13 6s2 6p6 7s2
Oxidation States+2, +3
Phase at STPSolid
CategoryActinoid
Period / Group7 / None
CAS Number7440-11-1

Electron Configuration

[Rn] 5f13 7s2

Shell n Subshell Electrons Cumulative
K11s22
L22s24
L22p610
M33s212
M33p618
M33d1028
N44s230
N44p636
N44d1046
N44f1460
O55s262
O55p668
O55d1078
O55f1391
P66s293
P66p699
Q77s2101
Total 101 101

Isotopes of Mendelevium

Mendelevium is monoisotopic: ²⁵⁸Md is its only naturally occurring stable isotope, accounting for 100% of all natural Mendelevium.

Isotope Symbol Protons Neutrons Abundance Stability
Mendelevium-258²⁵⁸Md101157traceStable

Abundance & Occurrence

Mendelevium is present in Earth's crust at approximately trace amounts by mass and at approximately trace amounts by mass throughout the universe.

Earth's Crust (ppm by mass)

Mendelevium
None ppm
Silicon (ref.)
277,000 ppm
Oxygen (ref.)
461,000 ppm

Universe (ppm by mass)

Mendelevium
None ppm
Helium (ref.)
230,000 ppm
Hydrogen (ref.)
739,000 ppm

Discovery & History

1955
Ghiorso, Harvey, Choppin, Thompson & Seaborg: The Berkeley team synthesised mendelevium-256 one atom at a time by bombarding einsteinium-253 with alpha particles, demonstrating that new elements could be discovered using single-atom detection: a landmark technique in heavy element chemistry.
1955
Albert Ghiorso's team: The element was named after Dmitri Mendeleev, creator of the periodic table, in recognition of his foundational contribution to chemistry: the first element named after Mendeleev, appropriately placed near the end of his own table.
1967
Oak Ridge Nuclear team: Md-258 (t½ = 51.5 days) was produced and its alpha and spontaneous fission decay modes characterised; mendelevium exhibited unexpected divalent chemistry in aqueous solution, the first heavy actinide to show this behaviour.

Safety & Handling

  • Alpha radiation: Mendelevium isotopes are alpha emitters; all are produced in atom-counting quantities in accelerator experiments and require handling in specialised radiochemical glove boxes with sensitive contamination monitoring.
  • Extremely short half-lives: The most accessible isotopes (Md-258, t½ = 51.5 days) decay rapidly; any accumulated sample grows its daughter isotopes quickly, complicating radiological characterisation.
  • No macroscopic quantities exist: Mendelevium has never been produced in quantities visible to the naked eye; practical hazard is negligible in absolute terms, but specific activity is high enough to require standard radiological precautions.
  • Regulatory controls: All work with mendelevium requires nuclear regulatory authority licensing and is conducted under nuclear safeguards and material accountancy requirements.

Real-World Uses

  • Actinide chemistry research: Mendelevium (Md-256, Md-258) is studied to determine whether the divalent (Md²⁺) oxidation state becomes the most stable for actinides beyond fermium, mirroring the lanthanide series behaviour, informing the theoretical understanding of the end of the actinide series.
  • Named in honour of Mendeleev: Element 101 was named mendelevium in honour of Dmitri Mendeleev, creator of the periodic table; the naming itself is of historical and cultural significance in the periodic table narrative.
  • No commercial applications: Only a few atoms of mendelevium are produced per experiment by accelerator bombardment; its properties are studied atom-by-atom and no applications outside fundamental research are feasible.

Downloadable Resources

Free periodic table reference sheets for classrooms, study sessions, and laboratory use.

Frequently Asked Questions

What is mendelevium used for?

Mendelevium has no practical applications. It is produced only in atom-at-a-time quantities in particle accelerators and can only be studied using ultra-sensitive radiochemical techniques. Its primary use is fundamental research into the chemical and nuclear properties of the actinide series, helping to understand how chemistry evolves at the end of the periodic table.

How was mendelevium discovered?

Mendelevium was synthesised in February 1955 by Albert Ghiorso, Bernard Harvey, Gregory Choppin, Stanley Thompson, and Glenn Seaborg at Berkeley. They bombarded a microscopic amount of einsteinium-253 (itself produced in a reactor) with helium ions in the 60-inch cyclotron. Only 17 atoms were produced in total. It was named after Dmitri Mendeleev, the chemist who created the periodic table and predicted the properties of undiscovered elements.

Is mendelevium radioactive?

Yes, all isotopes of mendelevium are radioactive. The longest-lived, Md-258, has a half-life of 51.5 days. The isotope first synthesised, Md-256, has a half-life of only 77 minutes. All mendelevium isotopes are produced one or a few atoms at a time and decay quickly, making experiments extremely challenging.

How did scientists detect just 17 atoms of mendelevium?

The original mendelevium experiment used a clever chemical technique: after bombardment, the einsteinium target was dissolved and the products were separated by ion exchange chromatography. The tiny amount of mendelevium produced was carried on an ion exchange resin column and eluted in a predictable position based on its expected ionic size (consistent with being a trivalent actinide). The individual mendelevium atoms were then detected by their alpha decay, which produces a characteristic energy signature measurable by a nuclear detector.